Nonwoven Technology Conference 2002 – Ottawa 13-16th May
This conference, organised by Marketing Technology Service of Kalamzoo Michigan, USA , and held in a dull and chilly Ottawa, Canada, focussed on the air-lay process. A truly international audience of 200+ delegates was treated to a first-class collection of papers and a surprisingly informative tour of the new, but fully operational, Concert air-lay plant in nearby Gatineau Quebec.
Air-Laid Supply and DemandPricie Hanna (John R Starr Inc) predicted a 4.4% annual growth for airlaid nonwovens in wipes for the next 5 years. Sales would increase from 6.2 billion m 2 in 2001 to 7.7 in 2006. In response to questions, Ms Hanna commented that there was a lot going on in diaper cores that had yet to reach the public domain. The development of long-fiber airlaid technology to compete with carding looked a promising development (see later). Wet-toilet tissue would progress slowly. While this was a great disappointment to many, she felt K-C would use the plant to make products other than “Cottonelle” while the shortfall existed. Airlaid History IBill Stevens (Consultant) reviewed the early development of airlaid technology, identifying Karl Kroyer as the visionary who first commercialised “dry-formed paper” and offered machinery for sale. Kroyer sold the technology to M&J in 1981, but in 1975, John Mosgaard left Kroyer and set up Scan-Web (renamed Dan-Web in 1981) to commercialise his own air-laying ideas. Independently, Honshu Paper (now part of Oji Paper) developed and commercialised a third process that they kept to themselves apart from licensing J&J. Current airlaid capacity was put at 480,000 tonnes/year excluding the vertical operations of P&G, K-C, PGI etc, for a market demanding about 350,000 tonnes. This came from 50 production lines making 18 different product lines. For the future, Mr Stevens saw: Hydroentangled airlaid as a key area for growth with 6 companies operating the combined processes this year and a further 3 lines coming on stream in the next. In response to questions, New Air-Lay system for Longer FibersJames Westphal (Troika Nonwovens) introduced two new machines: a fiber mixing system applicable to any air-lay process and a new air-lay head capable of handling fibers up to 50mm in length at higher throughput than woodpulp. Both machines used the principle of rapidly rotating spiked rolls to keep the suspension of fiber in air “fluid”. In the air-lay head these replaced the static screen which has been the main bottleneck of the Kroyer-based systems. The “GreenMat Star Fiber Mixer” was fitted into a line between the hammermill and the forming heads and was fed with pulp, recycle from the former, edge trim and bico fibers. In effect it replaced the transport fan, kept out of the hammermill those materials that could be damaged or reduce its efficiency and achieved very intimate mixing of all components. The payback came not only from the recycling element but from the ability to achieve strength specifications with lower levels of bicomponent fiber. On a 15000tpy line reducing the bico usage from 25% down to 15% would save $3.5M per year. ($350,000 per % bico eliminated) The new air-lay head or Star former (USP 6233781-B1) had been developed by ME Consulting – Aarhus (ex Dan-Web) as part of a project with the Danish Department of Agriculture to process flax into insulation board. Here Mr Westphal, who had been retained to help commercialise it, revealed that when used in conjunction with the mixer described above it could handle a tonne of fibers/metre/hr irrespective of length in the 4mm to 50mm range. Woodpulp, for reasons unclear, was restricted to half this productivity. Basis weights claimed ranged from 25 to 3000gsm. Asked about handling SAP, he said the powder could be added between forming heads or to the mixer. The mixer tower as currently designed would also handle a tonne/hour of fiber. With regard to fiber types processable, the gap setting of the star-forming rolls could be adjusted to suit the fiber. Cotton was not a problem. MD/CD ratios were typically 2:1. Troika is now working with a well-known producer of spunlace equipment to develop lightweight formers for nonwoven production. Airlaid History IIJesper Dobel (Danweb Forming International A/S) introduced the 3 rd generation air-lay drum former: Their pilot line was capable of 600m/min and they were now targeting 800m/min with 1000m/min thought to be ultimately achievable. He claimed 50% of the installed airlaid capacity for Dan-Web and Dan-Web Technology compared with 43% for M&J. Installations from 2000 on included: Asked if diaper makers would install their own airlaid core line, Mr Dobel thought not: the technology does not integrate well with diaper production, and diaper makers would lose flexibility if they made their own. Airless Spray Latex BondingPaul Scott (Vinamul Polymers) described the fruits of their collaboration with Nordson to develop an airless spray bonding system for uniform application of latex in concentrations up to 55% solids. Cross-cut spray nozzles were fed with latex at pressures between 100 and 1500 psi to give very precise surface coating (at ~50% solids), or penetration through the thickness of the pulp (at ~15% solids). Penetration depth could be adjusted by varying the dilution of the latex. The airless technology saved latex, reduced drying costs and reduced line contamination compared with conventional spraying. The system is already in commercial use on card-webs and spunlaid webs, and has been successfully tested on the M&J airlaid pilot line. The system worked best when heated latex (up to 130 0 C ) was sprayed, and this could mean the approach would work with low-melting polymers also. Uniformity of application was checked by visual inspection of the spray pattern using special illumination. In the pilot trials, coloured latex was used. Under-Utilised Technology?Tony Butterworth (Consultant) dealt with the evolution of airlaid up to 1985, using expired patents to bring out a number of issues that are still relevant today: Two-Layer Air-Lace Technology
Daniel Feroe (Rieter Perfojet) covered the difficulties of spun-lacing a pulp/long fiber mixture: So why bother? Because pulp is about one third of the price of viscose and great savings can arise by using it as a substitute. Compared with a 50/50 viscose/PET wipe costing €2.65/kg, Air-laced 50/50 Pulp/PET would be €1.89/kg. Mr Feroe could not recommend trying to make wipe fabric with fiber either side of the pulp. This is because the first fiber layer would be too thin to act as a pulp filter. Rieter Perfojet had also investigated combinations of their spunlaid process, airlaid pulp and hydroentanglement. Here the capital costs of a line were €21.7M but this approach gave the most efficient way of combining long-fiber and pulp at the lowest possible conversion cost (€1.32/kg for 50/50 spunlaid PP/Pulp at 60gsm).
In answer to questions, Mr Feroe added that at present there was no way of reclaiming the pulp washed through into the filter system. Spunlacing spunlaid webs was not a problem and needed only slightly more pressure than spunlacing staple. Finally all spunlaced systems needed chemical treatment of the water to prevent growth of microorganisms. 3000 Diapers/minute?Mike Jelinsky (Martin Automatic) plotted the output of diaper machines over the last 30 years and found it roughly linear from 150 to 650 diapers/min. Extrapolating, he concluded that 850/min would be possible by 2010, but postulated that if cores could be delivered to the line in web form rather than being made in-situ, then 3000 diapers/min would be possible. He listed the other advantages of pre-formed cores as: Less waste for the diaper maker With regard to other possible bottlenecks on the diaper line: However, with current diaper orientation the 3000 rate could only be reached by making two diapers side-by-side on the same line, i.e. running at 1500 “doubles” per minute. Making diapers sideways on would make the 3000 rate possible on a singles basis. Asked about the speed limit of running webs, Mr Jelinsky said that their Airnertia rolls would allow tension controlled unwinding at up to 2200 ft/min, at which speed the aerodynamic drag on the web became a significant source of uncontrolled tension. Dusting of the preformed webs would also become an issue at these speeds. Could drum formers be speeded up to allow 3000/minute? Maybe, but it would be cheaper to use preformed airlay. Airlaid History IIIHenning Skov Jensen (M&J Fibertech A/S) provided a catalogue of the new products possible with M&J forming technology, revisiting some themes of his presentations of the last couple of years: Line configurations now possible included one or more of thermal, latex, steaming, and calender bonding of single or multi-layer airlaid in combination with carding, spunlaying, meltblowing and glue lamination. The 5-layer diaper core concept, methods of reaching 2.5 tonnes/hr/m output and the Super-site concept were also mentioned. 17 installations of complete M&J lines were listed, along with the three air-formers on hydroentanglement lines at Albaad, Spuntech and Tenotex.
Frank Phillips of Source Options Consultants chaired most sessions. In response to questions, Mr Skov Jensen said: Why spunlace 100% pulp when hydrogen bonding was possible? Because spunlacing gave a much lower density product. Would a fluff-free core be possible in future? Mr Skov-Jensen thought not. Economics of Waste RecoveryJohn Cork (IBIS International Inc.) pointed out that the trend to larger machines using multibonding, or more specifically reduced levels of latex bonding, increased the scope for waste recycling on-site at the air-lay plant. A 20,000 tonne/year unit working at 90% material efficiency could be wasting 2000 tonnes, or about $1million, in pulp value per year. Latex bond air lay (LBAL) trim and waste – typically 15-25% latex content - tended to gum-up the shredders used to breakup 100% cellulose products and could not be recycled economically. If, as in the thermal or multi-bonded products, levels of latex below about 5% were used then recycling on-line became possible. The key piece of equipment used was the sort of shredder common in other waste textile reprocessing operations. This could be obtained from Temafa or Hollingsworth set up to deal with the airlaid material. IBIS would provide a complete system to deal with all waste from a 20000 tonne plant for about $1M giving a best case payback of 1 year. This would require 2 operators per shift on a three shift system. In response to questions he said the payback was based on recycling everything back into the process on site and valuing it at fresh pulp price, assumed to be $750/tonne. His reclaim units in diaper and femcare plants could however also separate and recover the SAP, and with TBAL, there was some value to be credited from the slight reduction in fresh bico needed when recycling was in use. Asked how much of the reclaimed product could be recycled before product quality suffered, he guessed 10-15%. However he was aware of a diaper producer making diaper cores out of 100% IBIS-recycled diaper waste from a nearby larger diaper plant. Calendering AirlaidJohannes Walterfang (Eduard Küsters Maschinenfabrik GmbH & Co KG) described the functions of a calender as: Roll materials could be steel, rubber coated or textile coated, and the other key variables were speed, temperature and nip pressure (or gap setting). High nip pressures resulted in deformation of the calender rolls, a deflection of up to a millimetre being possible over a 3 metre wide roll, giving unacceptably high pressures at the edges compared with the middle. This could be compensated for by crowning the rollers, crossing them at a slight angle, bending them, or best of all by using Küsters “swimming roll” system. Here the bottom roll was filled with hydraulic fluid which could be pressurised to deform the surface shape to match the distortion of the top roll over a wide range of nip pressures. For use on air-lay machines, bearings and drive systems had to be protected from the dusty environment, and the rolls were often horizontally opposed to minimise strain on the weak web as it transferred into the nip. Asked about pressures used, 200 N/mm of nip was the maximum. Temperatures ranged from 80 to 250 0 C, spunbonds down to 6gsm were being calender bonded, and brushes could be fitted to keep the rolls free of deposits. Calenders with special engravings could be used to perforate card webs, but holes were normally regarded as a problem. Denis Sens (Tembec Tartes S.A.- France) pointed out that the naturally hollow fibers extracted from wood had widely differing morphologies depending on whether the tree was deciduous or coniferous, grown in the cold north or the warm south, and whether pulp was made from forest thinnings and roundwood or from saw-mill waste. The key aspects of pulp fiber morphology were length, curl and width (if collapsed) or diameter (if still hollow). Tembec now measure these properties using the Techpap Morfi LB 01 analyser which scans a flowing suspension of fiber at the rate of 4000 fibers in 3 minutes. Hollow wall thickness is important and this needs a separate evaluation on the Metso Fiber Lab 3 instrument. TT also makes specialities which they hope may prove of interest in higher value air-lay products: Finer fibers give better softness, strength, rewet and printability. Coarser fibers give better acquisition rate, total capacity and porosity. Debonders make the fiber behave as if its finer while cross-linkers make it behave coarser. Hardwoods like eucalyptus tend to be too short and dusty for use in airlaid. The Future of FestooningRoberto Rahn (KorTec GmbH) compared the festooning systems developed by Gevas and KT Industries with the original KorTec process and a new KorTec process developed specifically for diaper core weights. The technology of festooning could be either single-lane (one endless ribbon per packed block) or multi-lane (as many ribbons as the width of the packer would take, splicing being used to join up the ends to create a single ribbon.) The multi-lane system required a rotary drum folder to build the pack, whereas the single-lane system could also use swivel-arm layering or KorTec's new plaiter machine. Current single-lane systems were poor for narrow ribbons (30mm), while the multi-lane systems were not viable for heavyweights (>450gsm diaper core). KorTec's single lane plating system which used a complex cross-folding belt mechanism to build a much larger package than possible with swivel-arm or rotary drum folders appeared to solve both problems. The cross-folder operated with a 2.4 metre length between folds compared with 1.2 m for the swivel arm and 0.9m for the rotary folder. This roughly doubled the length per pack and halved the number of folds. Despite the apparent additional mechanical complexity, Mr Rahn claimed no higher investment (in €/m 2 /year) than required for the swivel arm system, but stressed that the equipment would vary widely depending on the precise range of products it had to handle. For the future he saw the KorTec system being able to plait product directly into a container (did he mean a shipping container?), and the possibility of cores being delivered pre-cut to diaper size in special dispensers. Spooling was, he thought, poor in comparison to festooning and would decline. Through-Air DryingJ.A.Villalobos (Air-Therm Corp.) related the problems he had encountered starting up the first commercial air-lay machines: Ultra-Low Melt BicoIda Pittman (KoSa) covered the use of a lower, broader melting range polyethylene obtained from Dow's constrained geometry catalyst process. She compared a bicomponent fiber with this new polymer as a skin on a polyester core (“LM”), with their popular T255 bico that has a similar core with an ordinary polyethylene skin: In response to questions Ms Pittman said the LM fiber was sold at a premium. It would find application in the processing of heat sensitive materials or when bonding needed to occur during a drying operation. She thought the fiber would also find application in calendaring processes. She could not reveal the adhesion promoters used. High SAP Pre-formed CoresMark Bolyen (MTS Inc) reviewed data on airlaid diaper cores first given at the Aarhus NTC in 1999 adding new information on MTS's work with lighter weight structures. Here the thinking seemed to be to make a much thinner (100gsm) core, highly loaded with SAP and surfaced with a low-density bico acquisition layer to help contain the SAP and increase its strength. Multiple layers of this tested as a diaper core did not perform well because the SAP-containing part of the core would not pass fluid into the ADL below it. Wider widths of the composite could however be “ZS” folded in-line to give an effective 300gsm three-layer core. Such use of multiple layers of lighter webs would, Mr Bolyen thought allow much longer run times (more metres on any given spool or “brick”). Some core-comments: Wet-Laid/Airlaid CombinationsJim Hanson (MTS Inc) revisited the case for adding an air-lay former to a board machine to increase throughput and save energy in the container-board market. This time test data on the properties of various laminates made from ~200gsm of wet-laid northern softwood kraft at 25% moisture with 200 gsm of unspecified airlaid were provided. The laminates had been made at various laminating pressures in a slow calendering operation at 400 0 C. The presence of airlaid generally increased the thickness but reduced the tensiles and burst strengths. Interestingly, and here mimicking the performance of some advanced composites, the product with an airlaid layer between two wet-laids more than doubled the Tabor stiffness compared with the results from 2 layers of wet-laid alone.
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